@article {147,
	title = {Visible light driven photocatalytic evolution of hydrogen from water over CdS encapsulated MCM-48 materials.},
	journal = {RSC Advances},
	volume = {2},
	year = {2012},
	note = {CAPLUS AN 2012:860855(Journal; Online Computer File)},
	month = {2012///},
	pages = {5754 - 5767},
	publisher = {Royal Society of Chemistry},
	abstract = {CdS encapsulated cubic MCM-48 mesoporous photocatalysts were prepd. by a post-impregnation method.  Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), nitrogen adsorption isotherm, UV-visible diffuse reflectance spectroscopy (DRS), FT-IR spectrometry, XPS, at. absorption spectroscopy (AAS), and photoluminescence (PL) spectroscopy were employed for the characterization of the CdS incorporated MCM-48 siliceous materials.  MCM-48 was loaded with different amts. of CdS.  In the current study, all the samples showed photocatalytic activity under visible light (λ > 400 nm) irradn. for prodn. of hydrogen from splitting of water in the absence of Pt, which is usually used in photocatalytic splitting of water.  The photocatalytic activity of the CdS incorporated MCM-48 mesoporous photocatalysts was found to be dependent on the CdS loading and the pore size of MCM-48 siliceous support.  The highest solar hydrogen evolution rate by visible light irradn. from the splitting of water was detd. to be 1.81 mmol h-1 gCdS-1 and the apparent quantum yield was estd. to be 16.6\%. [on SciFinder(R)]},
	keywords = {cadmium sulfide encapsulation photocatalyst water hydrogen photocatalytic activity},
	isbn = {2046-2069},
	author = {Peng, Rui and Zhao, Dan and Baltrusaitis, Jonas and Wu, Chia-Ming and Koodali, Ranjit T.}
}
