<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Laird, Rebecca C.</style></author><author><style face="normal" font="default" size="100%">Nguyen, Nam P.</style></author><author><style face="normal" font="default" size="100%">Rusch, Sara F.</style></author><author><style face="normal" font="default" size="100%">Baltrusaitis, Jonas</style></author><author><style face="normal" font="default" size="100%">MacGillivray, Leonard R.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Noncentrosymmetric Packings Influenced by Electronic Properties of Products of Click Reactions.</style></title><secondary-title><style face="normal" font="default" size="100%">Crystal Growth &amp; Design</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">noncentrosym packing electronic property product click reaction D3LYP PXRD</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year></dates><publisher><style face="normal" font="default" size="100%">American Chemical Society</style></publisher><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">893 - 896</style></pages><isbn><style face="normal" font="default" size="100%">1528-7483</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Though 1,4-disubstituted 1,2,3-triazole rings have been utilized as electronic bridges in the soln. phase, the use of a triazole ring to serve as an electronic bridge of small mols. in the cryst. state has been underdeveloped.  Here two compds. with a central 1,4-disubstituted 1,2,3-triazole ring are synthesized to investigate the electronic bridging between terminal stilbazole and pyridine groups in the cryst. phase.  The electronic properties of the mols. are characterized through soln. phase UV-vis spectroscopy, single crystal X-ray diffractions, and d.-of-state and gas-phase DFT calcns.  We show that the electronic bridging behavior of a 1,4-disubstituted 1,2,3-triazole ring derived from a click reaction is maintained in the solid state by rare head-to-head (hh) packing in noncentrosym. crystal environments. [on SciFinder(R)]</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><notes><style face="normal" font="default" size="100%">CAPLUS AN 2014:263112(Journal; Online Computer File)</style></notes></record></records></xml>