<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Krylova, V.</style></author><author><style face="normal" font="default" size="100%">Dukstiene, N.</style></author><author><style face="normal" font="default" size="100%">Zalenkiene, S.</style></author><author><style face="normal" font="default" size="100%">Baltrusaitis, J.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Chemical and structural changes in polyamide based organic-inorganic hybrid materials upon incorporation of SeS2O2-6 precursor.</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Surface Science</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">hybrid</style></keyword><keyword><style  face="normal" font="default" size="100%">inorg</style></keyword><keyword><style  face="normal" font="default" size="100%">optical</style></keyword><keyword><style  face="normal" font="default" size="100%">org</style></keyword><keyword><style  face="normal" font="default" size="100%">polyamide</style></keyword><keyword><style  face="normal" font="default" size="100%">potassium selenotrithionate</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2017</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2017///</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">Elsevier B.V.</style></publisher><volume><style face="normal" font="default" size="100%">392</style></volume><pages><style face="normal" font="default" size="100%">634 - 641</style></pages><isbn><style face="normal" font="default" size="100%">0169-4332</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Composite org.-inorg. functional materials are of significant importance in various applications of science and technol.  In this work, physicochem. characterization of such composite materials obtained after the exposure of polyamide PA 6 to K2SeS2O6 precursor soln. was performed.  Chalcogenized polymer surface was characterized using X-ray diffraction, IR, and UV-vis spectroscopies while their bulk chem. anal. was performed using at. absorption spectroscopy.  Crystallite size was not found to change with the exposure to K2SeS2O6 precursor but PA 6 chain-chain sepn. decreased.  Importantly, IR and X-ray analyses showed chem. bonding taking place between the PA 6 and SeS2O2-6 ions via -NH- functional group.  A distinct change in bandgap, Eg, value was obsd. in UV-vis spectra due to the presence of SeS2O2-6, SeSO2-3 and Se2S2O2-6 ions formed via decompn. of the precursor material in acidic medium.  After extended 4 h halcogenation a distinct absorption due to the elemental selenium was also obsd. as obtained from Tauc plots. [on SciFinder(R)]</style></abstract><notes><style face="normal" font="default" size="100%">CAPLUS AN 2016:1512999(Journal; Online Computer File)</style></notes></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Krylova, V.</style></author><author><style face="normal" font="default" size="100%">Zalenkiene, S.</style></author><author><style face="normal" font="default" size="100%">Dukstiene, N.</style></author><author><style face="normal" font="default" size="100%">Baltrusaitis, J.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Modification of polyamide-CdS-CdSe composite material films with Ag using cation-cation exchange reaction.</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Surface Science</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">exchange reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">modification polyamide CdS CdSe composite material film Ag cation</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2015</style></year></dates><publisher><style face="normal" font="default" size="100%">Elsevier B.V.</style></publisher><volume><style face="normal" font="default" size="100%">351</style></volume><pages><style face="normal" font="default" size="100%">203 - 208</style></pages><isbn><style face="normal" font="default" size="100%">0169-4332</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Thin mixed CdSe-CdS-Ag2Se-Ag2S films were deposited on a polyamide 6 (PA) surface by successfully using a cation-exchange reaction between Cd2+ and Ag+ to convert CdSe-CdS into Ag2Se-Ag2S.  These were deposited using a K2SeS2O6 precursor soln. at 60 °C followed by cadmium acetate (Cd(CH3COO)2).  An aq. AgNO3 soln. was used as the Ag source.  XRD patterns showed a complex PA-Cd-S-Se-Ag film cryst. compn. with CdS, CdSe, Ag2S and Ag2Se peaks.  Calcd. dislocation d. ranged within 5-15 × 1013 lines·m-2 indicating high quality at. layers.  Atomic Absorption Spectroscopy (AAS) showed five- to ten-fold excess of chalcogens to metals in the thin films formed.  No chalcogenides were obsd. on the sample surface during XPS anal. after Ag exchange due to the desorption of CdS and CdSe layers, not diffused into the bulk of the polymer suggesting that silver chalcogenides were located subsurface, as opposed to the outermost layer, likely comprised of Ag2O. [on SciFinder(R)]</style></abstract><notes><style face="normal" font="default" size="100%">CAPLUS AN 2015:910421(Journal; Online Computer File)</style></notes></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sinkeviciute, D.</style></author><author><style face="normal" font="default" size="100%">Dukstiene, N.</style></author><author><style face="normal" font="default" size="100%">Baltrusaitis, J.</style></author><author><style face="normal" font="default" size="100%">Guobiene, A.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Principles of electrochemical reduction of Na2MoO4 on a Se/SnO2/glass surface.</style></title><secondary-title><style face="normal" font="default" size="100%">Chemine Technologija (Kaunas, Lithuania)</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">sodium molybdate electrochem redn tin dioxide selenium glass surface</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2010</style></year><pub-dates><date><style  face="normal" font="default" size="100%">2010///</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">Technologija</style></publisher><pages><style face="normal" font="default" size="100%">28 - 35</style></pages><isbn><style face="normal" font="default" size="100%">1392-1231</style></isbn><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Na2MoO4 electrochem. redn. from 0.22 mol/dm3 sodium citrate supporting soln. was investigated by the cyclic voltammetry, XPS and lateral force microscopy techniques.  Exptl. results have indicated that molybdenum oxide is initially deposited on the Se/SnO2/glass surface in a potential range from -0.20 V to -0.80 V.  XPS anal. exhibited the molybdenum oxide stoichiometry of 2.9.  The nucleation mechanism of MoOx onto Se/SnO2/glass surface was investigated by the current transient technique.  The deposition transients analyzed in the non-dimensional plots I2/I2m = f(t/tm) and I2/I2m = f(t/tm)2 have shown that MoOx nucleates according to a progressive mechanism.  The nucleation rate depends on Na2MoO4 concn. in the supporting electrolyte and on the deposition potential. [on SciFinder(R)]</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><notes><style face="normal" font="default" size="100%">CAPLUS AN 2010:548442(Journal)</style></notes></record></records></xml>